Brownian motion, hydrodynamics, and the osmotic pressure

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Brownian motion, hydrodynamics, and the osmotic pressure

It is shown that the osmotic pressure of a colloidal dispersion can be interpreted as the isotropic part of the macroscopic particle stress in the suspension. The particle stress is in turn expressible in terms of hydrodynamic interactions among the suspended particles. Thus, there is a completely mechanical definition of the osmotic pressure, just as there is for the pressure in a molecular fl...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 1993

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.464105